4-Nitrodiphenylamine

Modify Date: 2024-01-01 22:51:21

4-Nitrodiphenylamine Structure
4-Nitrodiphenylamine structure
Common Name 4-Nitrodiphenylamine
CAS Number 836-30-6 Molecular Weight 214.220
Density 1.3±0.1 g/cm3 Boiling Point 382.6±25.0 °C at 760 mmHg
Molecular Formula C12H10N2O2 Melting Point 132-135 °C(lit.)
MSDS Chinese USA Flash Point 185.2±23.2 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 4-Nitrodiphenylamine
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.3±0.1 g/cm3
Boiling Point 382.6±25.0 °C at 760 mmHg
Melting Point 132-135 °C(lit.)
Molecular Formula C12H10N2O2
Molecular Weight 214.220
Flash Point 185.2±23.2 °C
Exact Mass 214.074234
PSA 57.85000
LogP 3.74
Vapour Pressure 0.0±0.9 mmHg at 25°C
Index of Refraction 1.666
Water Solubility INSOLUBLE

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
JJ9600000
CHEMICAL NAME :
Diphenylamine, 4-nitro-
CAS REGISTRY NUMBER :
836-30-6
BEILSTEIN REFERENCE NO. :
2051910
LAST UPDATED :
199710
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C12-H10-N2-O2
MOLECULAR WEIGHT :
214.24
WISWESSER LINE NOTATION :
WNR DMR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,66,1990 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>7940 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,66,1990
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
4 gm/kg
TOXIC EFFECTS :
Behavioral - excitement Behavioral - muscle contraction or spasticity Blood - hemorrhage
REFERENCE :
TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 8,126,1966
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>7940 mg/kg
TOXIC EFFECTS :
Behavioral - food intake (animal) Behavioral - changes in motor activity (specific assay)
REFERENCE :
ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,66,1990 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4095 No. of Facilities: 6 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 348 (estimated) No. of Female Employees: 34 (estimated)

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S37/39
RIDADR 3077
WGK Germany 3
RTECS JJ9600000
Packaging Group III
Hazard Class 9
HS Code 2921440000

 Synthetic Route

 Customs

HS Code 2921440000
Summary 2921440000. diphenylamine and its derivatives; salts thereof. VAT:17.0%. Tax rebate rate:17.0%. . MFN tariff:6.5%. General tariff:30.0%

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 Synonyms

p-Nitrodiphenylamine
4-Nitro-N-phenylaniline
N-(4-Nitrophenyl)-N-phenylamine
EINECS 212-646-2
Benzenamine, 4-nitro-N-phenyl-
4-Nitrodiphenylamine
MFCD00007301