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丁香乙酮

丁香乙酮用途

【用途一】
植物组织培养基常用添加剂

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丁香乙酮名称

[ CAS 号 ]:
2478-38-8

[ 中文名 ]:
乙酰丁香酮

[ 英文名 ]:
3',5'-Dimethoxy-4'-hydroxyacetophenone

[中文别名 ]:

[英文别名 ]:

Ethanone,1-(4-hydroxy-3,5-dimethoxyphenyl)
3',5'-Dimethoxy-4'-Hydroxyacetophenone
1-(4-Hydroxy-3,5-dimethoxyphenyl)ethanone
Ethanone, 1-(4-hydroxy-3,5-dimethoxyphenyl)-
Acetosyringenin
3,5-Dimethoxy-4-hydroxyacetophenone
1-(4-hydroxy-3,5-dimethoxy-phenyl)-ethanone
3‘,5‘-Dimethoxy-4‘-hydroxyacetophenone
Syringylethanone
MFCD00008748

丁香乙酮生物活性

[ 描述 ]:

Acetosyringone 是一种酚类化合物,从受伤的植物细胞中产生。virA 基因能够编码膜结合蛋白,感知 Acetosyringone,使自身磷酸化并激活 vir 基因产物,后者刺激自身及其他 vir 基因的转录[1]。Acetosyringone 能够增强 Agrobacterium 介导的杜氏盐藻的高效转化[2]。

[ 相关类别 ]:

信号通路 >> 其他 >> 其他

研究领域 >> 其他

天然产物 >> 酚类

[体外研究]

乙酰丁香酮是来自受伤植物细胞的酚类化合物,能够编码膜结合激酶的virA基因磷酸化自身并激活virG基因产物,从而刺激其他vir基因及其自身的转录[1]。乙酰丁香酮增强农杆菌菌株的有效杜氏藻转化[2]。

[参考文献]

[1]. Xi J, et al. Acetosyringone treatment duration affects large T-DNA molecule transfer to rice callus. BMC Biotechnol. 2018 Aug 9;18(1):48.

[2]. Srinivasan R, et al. Synergistic Action of D-Glucose and Acetosyringone on Agrobacterium Strains for Efficient Dunaliella Transformation. PLoS One. 2016 Jun 28;11(6):e0158322.

[相关活性小分子]

丁香乙酮物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
334.7±37.0 °C at 760 mmHg

[ 熔点 ]:
124-127 °C(lit.)

[ 分子式 ]:
C₁₀H₁₂O₄

[ 分子量 ]:
196.200

[ 闪点 ]:
131.7±20.0 °C

[ 精确质量 ]:
196.073563

[ PSA ]:
55.76000

[ LogP ]:
1.23

[ 外观性状 ]:
淡棕色粉末

[ 蒸汽压 ]:
0.0±0.8 mmHg at 25°C

[ 折射率 ]:
1.528

[ 储存条件 ]:
室温

[ 水溶解性 ]:
soluble

丁香乙酮MSDS

丁香乙酮毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AM8440000

CHEMICAL NAME :: Acetophenone, 3,5-dimethoxy-4-hydroxy-

CAS REGISTRY NUMBER :: 2478-38-8

BEILSTEIN REFERENCE NO. :: 1966119

LAST UPDATED :: 199612

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C10-H12-O4

MOLECULAR WEIGHT :: 196.22

WISWESSER LINE NOTATION :: 1VR DQ CO1 EO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >10 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: BCTKAG Bromatologia i Chemia Toksykologiczna. (Ars Polona, POB 1001, 00-068 Warsaw 1, Poland) V.4- 1971- Volume(issue)/page/year: 14,301,1981

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 650 mg/kg

TOXIC EFFECTS :: Behavioral - altered sleep time (including change in righting reflex)

REFERENCE :: JMCMAR Journal of Medicinal Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC 20037) V.6- 1963- Volume(issue)/page/year: 7,178,1964

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丁香乙酮安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
AM8440000

[ 海关编码 ]:
2914509090

丁香乙酮合成路线

丁香乙酮上下游产品

丁香乙酮上游产品

丁香乙酮下游产品

丁香乙酮海关

[ 海关编码 ]: 2914509090

[ 中文概述 ]:
2914509090 含其他含氧基的酮. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
HS:2914509090 other ketones with other oxygen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

丁香乙酮文献

The RING E3 Ligase KEEP ON GOING Modulates JASMONATE ZIM-DOMAIN12 Stability.

Plant Physiol. 169 , 1405-17, (2015)

Jasmonate (JA) signaling in plants is mediated by the JASMONATE ZIM-DOMAIN (JAZ) proteins that repress the activity of several transcription factors regulating JA-inducible gene expression. The hormon...

Cellular apoptosis and cytotoxicity of phenolic compounds: a quantitative structure-activity relationship study.

J. Med. Chem. 48 , 7234-42, (2005)

In this comprehensive study on the caspase-mediated apoptosis-inducing effect of 51 substituted phenols in a murine leukemia cell line (L1210), we determined the concentrations needed to induce caspas...

Identification of rice cornichon as a possible cargo receptor for the Golgi-localized sodium transporter OsHKT1;3.

J. Exp. Bot. 66 , 2733-48, (2015)

Membrane proteins are synthesized and folded in the endoplasmic reticulum (ER), and continue their path to their site of residence along the secretory pathway. The COPII system has been identified as ...

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