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特戊基过氧化氢

特戊基过氧化氢名称

[ CAS 号 ]:
3425-61-4

[ 中文名 ]:
特戊基过氧化氢

[ 英文名 ]:
tert-Amyl hydroperoxide

[中文别名 ]:

1,1-二甲丙基过氧化氢

[英文别名 ]:

Trigonox TAHP
1,1-Dimethylpropyl hydroperoxide
t-Amyl hydroperoxide
tert-Amylhydroperoxide
tertiary amyl hydroperoxide
2-methylbutane hydroperoxide
1,1-dimethyl-propylhydroperoxid
Hydroperoxide,1,1-dimethylpropyl
tert-pentyl hydroperoxide

特戊基过氧化氢物理化学性质

[ 密度 ]:
0.905 g/cm3

[ 沸点 ]:
144.6ºC

[ 分子式 ]:
C₅H₁₂O₂

[ 分子量 ]:
104.14800

[ 精确质量 ]:
104.08400

[ PSA ]:
29.46000

[ LogP ]:
1.66460

[ 折射率 ]:
1.409

特戊基过氧化氢毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SC3067000

CHEMICAL NAME :: tert-Pentyl hydroperoxide

CAS REGISTRY NUMBER :: 3425-61-4

BEILSTEIN REFERENCE NO. :: 1731878

LAST UPDATED :: 199712

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C5-H12-O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 864 mg/kg

TOXIC EFFECTS :: Behavioral - general anesthetic Kidney, Ureter, Bladder - hematuria Blood - methemoglobinemia-carboxyhemoglobin

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 22(7),51,1978

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1510 mg/m3

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - changes in lung weight Blood - methemoglobinemia-carboxyhemoglobin Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - cytochrome oxidases (including oxidative phosphorylation)

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(5),53,1981

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 225 mg/kg

TOXIC EFFECTS :: Behavioral - general anesthetic Kidney, Ureter, Bladder - hematuria Blood - methemoglobinemia-carboxyhemoglobin

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 22(7),51,1978

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 450 mg/kg

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - changes in lung weight Blood - methemoglobinemia-carboxyhemoglobin Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - cytochrome oxidases (including oxidative phosphorylation)

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(5),53,1981

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1370 mg/m3

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - changes in lung weight Blood - methemoglobinemia-carboxyhemoglobin Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - cytochrome oxidases (including oxidative phosphorylation)

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(5),53,1981

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 275 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,21,1982 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 5 mg/m3;Skin JAN 1993

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特戊基过氧化氢安全信息

[ 海关编码 ]:
2909600000

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特戊基过氧化氢海关

[ 海关编码 ]: 2909600000

[ 中文概述 ]:
2909600000 过氧化醇、过氧化醚、过氧化酮及其卤化、磺化、硝化、亚硝化衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2909600000 alcohol peroxides, ether peroxides, ketone peroxides and their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%