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2-异亚硝基苯乙酮

2-异亚硝基苯乙酮名称

[ CAS 号 ]:
532-54-7

[ 中文名 ]:
2-异亚硝基苯乙酮

[ 英文名 ]:
a-Oxobenzeneacetaldehyde Aldoxime

[中文别名 ]:

[英文别名 ]:

(2E)-2-(Hydroxyimino)-1-phenylethanone
Benzeneacetaldehyde, α-oxo-, aldoxime
EINECS 208-539-5
2-Oxo-2-phenylacetaldehyde oxime
2-Hydroxyiminoacetophenone
ω-(Hydroxyimino)acetophenone
Isonitrosoacetophenone
(2E)-2-hydroxyimino-1-phenylethanone
Phenylglyoxaldoxim
a-Oxobenzeneacetaldehyde Aldoxime

2-异亚硝基苯乙酮物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
305.7±25.0 °C at 760 mmHg

[ 熔点 ]:
123-125 °C

[ 分子式 ]:
C₈H₇NO₂

[ 分子量 ]:
149.147

[ 闪点 ]:
138.7±23.2 °C

[ 精确质量 ]:
149.047684

[ PSA ]:
49.66000

[ LogP ]:
1.41

[ 外观性状 ]:
米色至黄色粉末

[ 蒸汽压 ]:
0.0±0.7 mmHg at 25°C

[ 折射率 ]:
1.543

[ 储存条件 ]:
2-8°C

[ 水溶解性 ]:
SOLUBLE IN COLD WATER

2-异亚硝基苯乙酮MSDS

2-异亚硝基苯乙酮毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MD3325000

CHEMICAL NAME :: Glyoxal, 1-phenyl-, 2-oxime

CAS REGISTRY NUMBER :: 532-54-7

BEILSTEIN REFERENCE NO. :: 2041691

LAST UPDATED :: 199709

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C8-H7-N-O2

MOLECULAR WEIGHT :: 149.16

WISWESSER LINE NOTATION :: QNU1VR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,27,1953

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 75 mg/kg

TOXIC EFFECTS :: Behavioral - coma

REFERENCE :: JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 119,522,1957

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2-异亚硝基苯乙酮安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H312-H332

[ 警示性声明 ]:
P280

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S36/37-S24/25

[ 危险品运输编码 ]:
2811

[ WGK德国 ]:
3

[ RTECS号 ]:
MD3325000

[ 海关编码 ]:
2928000090

2-异亚硝基苯乙酮合成路线

2-异亚硝基苯乙酮上下游产品

2-异亚硝基苯乙酮上游产品

2-异亚硝基苯乙酮下游产品

2-异亚硝基苯乙酮海关

[ 海关编码 ]: 2928000090

[ 中文概述 ]:
2928000090 其他肼（联氨）及胲（羟胺）的有机衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

2-异亚硝基苯乙酮文献

Biotransformation of isonitrosoacetophenone (2-keto-2-phenyl-acetaldoxime) in tobacco cell suspensions.

Biotechnol. Lett. 34(7) , 1351-6, (2012)

Nicotiana tabacum cell suspensions, 2 g wet wt/ml, rapidly took up 1 mM isonitrosoacetophenone (INAP), a plant-derived stress metabolite with anti-oxidative and anti-fungal properties, producing 4'-he...

Neuropathy target esterase: rates of turnover in vivo following covalent inhibition with phenyl di-n-pentylphosphinate.

J. Neurochem. 51(4) , 1097-101, (1988)

Phenyl di-n-pentylphosphinate is a reasonably stable easily synthesized inhibitor of neuropathy target esterase (NTE) with low anticholinesterase activity. Like phenylmethylsulphonyl fluoride it prote...

Synthesis and evaluation of 4-(3-methyl-2-butenoxy) isonitrosoacetophenone, a radiation-induced stress metabolite in Citrus.

Phytochemistry 50(6) , 983-9, (1999)

The time- and dose-dependent occurrence of 4-(3-methyl-2-butenoxy)isonitrosoacetophenone, a gamma-irradiation-induced stress metabolite was investigated. The chemical synthesis of the compound is repo...

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