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邻溴苯甲醚

邻溴苯甲醚用途

【用途一】
用于合成香料

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邻溴苯甲醚名称

[ CAS 号 ]:
578-57-4

[ 中文名 ]:
2-溴苯甲醚

[ 英文名 ]:
bromoanisole

[中文别名 ]:

[英文别名 ]:

2-Bromoanisole
2-Bromophenyl methyl ether
Benzene, 1-bromo-2-methoxy-
bromoanisole
1-Bromo-2-methoxybenzene
EINECS 209-425-8
MFCD00000064

邻溴苯甲醚物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
216.0±0.0 °C at 760 mmHg

[ 熔点 ]:
2 °C(lit.)

[ 分子式 ]:
C₇H₇BrO

[ 分子量 ]:
187.034

[ 闪点 ]:
96.7±0.0 °C

[ 精确质量 ]:
185.968018

[ PSA ]:
9.23000

[ LogP ]:
2.70

[ 外观性状 ]:
无色或淡黄色液体

[ 蒸汽压 ]:
0.2±0.4 mmHg at 25°C

[ 折射率 ]:
1.539

[ 储存条件 ]:
库房通风低温干燥

[ 稳定性 ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

邻溴苯甲醚MSDS

邻溴苯甲醚毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: BZ8500000

CHEMICAL NAME :: Anisole, o-bromo-

CAS REGISTRY NUMBER :: 578-57-4

BEILSTEIN REFERENCE NO. :: 1859996

LAST UPDATED :: 199701

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C7-H7-Br-O

MOLECULAR WEIGHT :: 187.05

WISWESSER LINE NOTATION :: ER BO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2466 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 44(12),19,1979

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1544 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 44(12),19,1979

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邻溴苯甲醚安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves

[ 危害码 (欧洲) ]:
N:Dangerousfortheenvironment;

[ 风险声明 (欧洲) ]:
51/53

[ 安全声明 (欧洲) ]:
S61-S24/25

[ 危险品运输编码 ]:
UN 3082 9/PG 3

[ WGK德国 ]:
2

[ RTECS号 ]:
BZ8500000

[ 危险类别 ]:
9.0

[ 海关编码 ]:
29093038

邻溴苯甲醚合成路线

邻溴苯甲醚上下游产品

邻溴苯甲醚上游产品

邻溴苯甲醚下游产品

邻溴苯甲醚海关

[ 海关编码 ]: 2909309090

[ 中文概述 ]:
2909309090 其他芳香醚及其卤化衍生物、磺化、硝化衍生物（包括亚硝化衍生物）。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

邻溴苯甲醚文献

Synthesis, modification, and characterization of a family of homologues of exo-calix

J. Org. Chem. 65(17) , 5185-96, (2000)

A general strategy for the preparation of the family of exo-[n.m.n.m]metacyclophanes (n,m > or = 3) in 6-steps (starting from 2-bromoanisole) that utilizes a [2 + 2] approach to furnish the exo-metacy...

4,4'-Unsymmetrically substituted 3,3'-biphenyl alpha helical proteomimetics as potential coactivator binding inhibitors.

Bioorg. Med. Chem. 22(2) , 917-26, (2014)

A series of unsymmetrically substituted biphenyl compounds was designed as alpha helical proteomimetics with the aim of inhibiting the binding of coactivator proteins to the nuclear hormone receptor c...

Diffusion coefficients of 2-fluoroanisole, 2-bromoanisole, allylbenzene and 1, 3-divinylbenzene at infinite dilution in supercritical carbon dioxide Suárez-Iglesias O, et al.

Fluid Phase Equilib. 260(2) , 279-86, (2007)

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