丙酮醛
丙酮醛用途
丙酮醛名称
[ CAS 号 ]:
78-98-8
[ 中文名 ]:
丙酮醛
[ 英文名 ]:
Methylglyoxal
[中文别名 ]:
[英文别名 ]:
- 2-oxo-propanal
- 2-oxo-Propionaldehyde
- methyl-glyoxal
- α-Ketopropionaldehyde
- acetylformaldehyde
- 2-keto Propionaldehyde
- Pyruvaldehyde (8CI)
- Ketopropionaldehyde
- 2-Oxopropanal
- MFCD00006960
丙酮醛生物活性
丙酮醛物理化学性质
[ 密度 ]:
1.0±0.1 g/cm3
[ 沸点 ]:
72.0±0.0 °C at 760 mmHg
[ 熔点 ]:
25 °C
[ 分子式 ]:
C3H4O2
[ 分子量 ]:
72.063
[ 闪点 ]:
2.5±4.4 °C
[ 精确质量 ]:
72.021126
[ PSA ]:
34.14000
[ LogP ]:
-0.80
[ 外观性状 ]:
透明黄色略粘性液体带有一种辛辣气味淡的酸味
[ 蒸汽压 ]:
120.9±0.1 mmHg at 25°C
[ 折射率 ]:
1.364
[ 储存条件 ]:
2-8°C
[ 水溶解性 ]:
>=10 g/100 mL at 17 ºC
丙酮醛MSDS
丙酮醛毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- UZ0700000
- CHEMICAL NAME :
- Pyruvaldehyde
- CAS REGISTRY NUMBER :
- 78-98-8
- BEILSTEIN REFERENCE NO. :
- 0906750
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 31
- MOLECULAR FORMULA :
- C3-H4-O2
- MOLECULAR WEIGHT :
- 72.07
- WISWESSER LINE NOTATION :
- VHV1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1165 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 179 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 252 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- Unscheduled DNA synthesis
MUTATION DATA
- TYPE OF TEST :
- Mutation test systems - not otherwise specified
- TEST SYSTEM :
- Rodent - guinea pig Cells - not otherwise specified
- DOSE/DURATION :
- 6600 umol/L
- REFERENCE :
- CBINA8 Chemico-Biological Interactions. (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1969- Volume(issue)/page/year: 38,339,1982 *** REVIEWS *** IARC Cancer Review:Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 51,443,1991 IARC Cancer Review:Human No Available Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 51,443,1991 IARC Cancer Review:Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 51,443,1991
丙酮醛安全信息
[ 符号 ]:
GHS07
[ 信号词 ]:
Warning
[ 危害声明 ]:
H319
[ 警示性声明 ]:
P305 + P351 + P338
[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ 危害码 (欧洲) ]:
Xn:Harmful;
[ 风险声明 (欧洲) ]:
R22;R36
[ 安全声明 (欧洲) ]:
S26-S36
[ 危险品运输编码 ]:
NONH for all modes of transport
[ WGK德国 ]:
-
[ 海关编码 ]:
2914400090
丙酮醛合成路线
丙酮醛上下游产品
丙酮醛上游产品
丙酮醛下游产品
丙酮醛制备
1.由丙酮或丙醛经二氧化硒氧化或1,2-丙二醇在铜粉催化下经空气氧化制得。
2. 通过加热异亚硝基丙酮和稀硫酸得到;也可通过在碳酸钙存在下蒸馏二羟基丙酮的稀溶液而得到。
丙酮醛海关
[ 海关编码 ]: 2914400090
[ 中文概述 ]:
2914400090 其他酮醇及酮醛。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装
[ Summary ]:
2914400090 other ketone-alcohols and ketone-aldehydes。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%
丙酮醛文献
Biochem. J. 464(3) , 387-99, (2014)
The aaoSo gene from Streptococcus oligofermentans encodes a 43 kDa flavoprotein, aminoacetone oxidase (SoAAO), which was reported to possess a low catalytic activity against several different L-amino ...
The Chilean wild raspberry (Rubus geoides Sm.) increases intracellular GSH content and protects against H2O2 and methylglyoxal-induced damage in AGS cells.Food Chem. 194 , 908-19, (2015)
The Chilean raspberry Rubus geoides Sm. (Rosaceae) is a native species occurring in the Patagonia. Five R. geoides samples were assessed for phenolic content and composition, antioxidant activity, eff...
Novel HPLC--Fluorescence methodology for the determination of methylglyoxal and glyoxal. Application to the analysis of monovarietal wines "Ribera del Guadiana".Food Chem. 187 , 159-65, (2015)
The determination and quantification of α-dicarbonyl compounds, glyoxal and methylglyoxal, in "Ribera del Guadiana" monovarietal wines (Extremadura, Spain) without sample clean-up has been carried out...
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¥50.9/50g
¥477.9/1kg
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产品详情:丙酮醛
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相关化合物
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