氰化亚铜

一般危化品
氰化亚铜结构式
氰化亚铜结构式
常用名 氰化亚铜 英文名 Copper cyanide
CAS号 544-92-3 分子量 89.56340
密度 2.92 g/mL at 25 °C(lit.) 沸点 N/A
分子式 CCuN 熔点 474 °C(lit.)
MSDS 中文版 美版 闪点 140°C(lit.)
符号 GHS06 GHS09
GHS06, GHS09
信号词 Danger

Iron(VI) and iron(V) oxidation of copper(I) cyanide.

Environ. Sci. Technol. 39(10) , 3849-54, (2005)

Copper(Il) cyanide (Cu(CN)4(3-)) in the gold mine industry presentsthe biggest concern in cyanide management because it is much more stable than free cyanide. Cu(CN)4(3-) is highlytoxic to aquatic life; therefore, environmentally friendly techniques are requi...

The first precise molecular structure of a monomeric transition metal cyanide, copper(I) cyanide.

J. Am. Chem. Soc. 124(20) , 5895-901, (2002)

Copper(I) cyanide is an important reagent in organic, organometallic, and supramolecular chemistry because of both the copper center and the versatile cyanide ligand. Solid-phase CuCN and many of its derivatives show oligomeric or polymeric structures, a trai...

Crystal Structures of a Series of Complexes Produced by Reaction of Copper(I) Cyanide with Diamines.

Inorg. Chem. 38 , 984, (1999)

A new synthetic procedure developed recently in our laboratories has made possible the synthesis of variety of new complexes of CuCN with diamines. Synthesis was effected by adding the ligand to a solution of CuCN in aqueous sodium thiosulfate. This procedure...

Crystal Structures of a Family of New Copper(I) Cyanide Complexes of Thiourea and Substituted Thioureas.

Inorg. Chem. 35(11) , 3145-3153, (1996)

The syntheses and crystal structures of the first cyanide, sulfur mixed ligand copper(I) complexes are reported. The first complex of the family was discovered when (CuCN)(3)(C(6)H(12)N(4))(2) (1) (C(6)H(12)N(4) = hexamethylenetetramine) was treated with aque...