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N-[3,5-二(三氟甲基)苯基]-N'-[(9R)-6'-甲氧基奎宁-9-基]硫脲

N-[3,5-二(三氟甲基)苯基]-N'-[(9R)-6'-甲氧基奎宁-9-基]硫脲结构式
N-[3,5-二(三氟甲基)苯基]-N'-[(9R)-6'-甲氧基奎宁-9-基]硫脲结构式
品牌特惠专场
常用名 N-[3,5-二(三氟甲基)苯基]-N'-[(9R)-6'-甲氧基奎宁-9-基]硫脲 英文名 1-(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-3-((1R)-(6-METHOXYQUINOLIN-4-YL)((2R,4S,5R)-5-VINYLQUINUCLIDIN-2-YL)METHYL)THIOUREA
CAS号 852913-25-8 分子量 594.61400
密度 N/A 沸点 N/A
分子式 C29H28F6N4OS 熔点 150°C
MSDS 中文版 美版 闪点 N/A
符号 GHS06
GHS06
信号词 Danger

Urea- and thiourea-substituted cinchona alkaloid derivatives as highly efficient bifunctional organocatalysts for the asymmetric addition of malonate to nitroalkenes: inversion of configuration at C9 dramatically improves catalyst performance.

Angew. Chem. Int. Ed. Engl. 44 , 6367-6370, (2005)

Highly enantioselective conjugate addition of nitromethane to chalcones using bifunctional cinchona organocatalysts.

Org. Lett. 7 , 1967-1969, (2005)

Cinchona alkaloid-derived chiral bifunctional thiourea organocatalysts were synthesized and applied in the Michael addition between nitromethane and chalcones with high ee and chemical yields.