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三氟甲烷磺酸2-萘酯

三氟甲烷磺酸2-萘酯结构式
三氟甲烷磺酸2-萘酯结构式
品牌特惠专场
常用名 三氟甲烷磺酸2-萘酯 英文名 2-Naphthyl trifluoromethanesulfonate
CAS号 3857-83-8 分子量 276.23200
密度 1.493g/cm3 沸点 343.8ºC at 760 mmHg
分子式 C11H7F3O3S 熔点 30-32ºC(lit.)
MSDS 中文版 美版 闪点 >230 °F
符号 GHS05
GHS05
信号词 Danger

Palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides.

J. Am. Chem. Soc. 132 , 14076, (2010)

The palladium-catalyzed conversion of aryl and vinyl triflates to aryl and vinyl halides (bromides and chlorides) has been developed using dialkylbiaryl phosphine ligands. A variety of aryl, heteroaryl, and vinyl halides can be prepared via this method in goo...

Regiochemical control and suppression of double bond isomerization in the Heck arylation of 1-(methoxycarbonyl)-2, 5-dihydropyrrole. Sonesson C, et al.

J. Org. Chem. 61(14) , 4756-4763, (1996)

Influence of the catalyst on the Pd0-mediated reactions of BrZnCH(CH3) COOtBu with vinyl and aryl triflates. Orsini F, et al.

J. Organomet. Chem. 367(3) , 375-382, (1989)