3,5-DI-TERT-BUTYL-O-BENZOQUINONE
3,5-DI-TERT-BUTYL-O-BENZOQUINONE structure
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Common Name | 3,5-DI-TERT-BUTYL-O-BENZOQUINONE | ||
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| CAS Number | 3383-21-9 | Molecular Weight | 220.307 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 302.7±15.0 °C at 760 mmHg | |
| Molecular Formula | C14H20O2 | Melting Point | 112-114 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 120.6±6.0 °C | |
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Reactions of the phosphinidene-bridged complexes [Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph) with electrophiles based on p-block elements.
Dalton Trans. 41(48) , 14498-513, (2012) The title complexes reacted readily with the methylating agents MeI and CF(3)SO(3)Me, chalcogens (O(2), S(8)) and borane adducts BH(3)·L (L = THF, N(t)Bu(3), PPh(3)) to initially give the corresponding neutral or cationic derivatives of the type [Fe(2)Cp(2){μ... |
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Versatile chemical transformations of benzoxazole based ligands on complexation with 3d-metal ions.
Inorg. Chem. 51(4) , 2588-96, (2012) Two benzoxazoles derivative ligands were synthesized from the condensation of 3,5-di-tert-butyl-o-benzoquinone (DTBBQ) with ethanolamine or 1,3-diamino-2-hydroxypropane in methanol. Condensation of DTBBQ with ethanolamine gives the expected 5,7-di-tert-butyl-... |
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Determination of natural thiols by liquid chromatography after derivatization with 3,5-di-tert.-butyl-1,2-benzoquinone.
J. Chromatogr. A. 420(2) , 404-10, (1987)
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Stability of colistimethate sodium in aqueous solution.
J. Inorg. Biochem. 103(3) , 389-95, (2009) Colistimethate sodium, increasingly used to treat multidrug-resistant Gram-negative infections, spontaneously hydrolyzes to form colistin A (polymyxin E1) and B (polymyxin E2/B) when mixed with water. High levels of these active breakdown products at the time... |
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A dicopper complex with distant metal centers. Structure, magnetic properties, electrochemistry and catecholase activity.
J. Inorg. Biochem. 102(5-6) , 1227-35, (2008) The crystal structure and magnetic properties of a dinuclear copper(II) complex of the ligand [2,8-dimethyl-5,11-di-(dimethylethyleneamine) 1,4,5,6,7,10,11,12-octahydroimidazo [4,5-h] imidazo [4,5-c] [1,6]diazecine] dimeim have been investigated. Also, its ca... |
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Change in reaction pathway in the reduction of 3,5-di-tert-butyl-1,2-benzoquinone with increasing concentrations of 2,2,2-trifluoroethanol.
J. Phys. Chem. B 110(43) , 22043-7, (2006) The electrochemical reduction of 3,5-di-tert-butyl-1,2-benzoquinone, 1, has been studied in acetonitrile with added 2,2,2-trifluoroethanol, 2. At low concentrations of 2 the reaction proceeds by the following pathway: reduction of the quinone (Q) to its anion... |
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A disposable voltammetric cell for determining the titratable acidity in vinegar.
Anal. Sci. 19(11) , 1473-6, (2003) A disposable voltammetric cell using three pencil leads as working, reference, and counter electrodes was developed for determining the titratable acidity, i.e. the acid content in vinegar. The materials of the pencil leads were graphite-reinforcement carbons... |
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The "Corey's reagent," 3,5-di-tert-butyl-1,2-benzoquinone, as a modifying agent in the synthesis of fluorescent and double-headed nucleosides.
Nucleosides Nucleotides Nucleic Acids 28(5) , 464-72, (2009) A new method for the synthesis of fluorescent nucleosides has been developed. It has been shown that a reaction of benzoquinone with aminopropenyl group at C-5-position of 2'-deoxyuridine or 2'-deoxycytidine and aminopropynyl group at the C-7-position of 8-az... |
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Hetero Diels-Alder reactions of 3, 5-di-tert-butyl-o-benzoquinone with acyclic dienes: novel synthesis of 1, 4-benzodioxines. Nair V and Kumar S.
J. Chem. Soc. Chem. Commun. 11 , 1341-42, (1994)
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