Thiophenol
Thiophenol structure
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Common Name | Thiophenol | ||
|---|---|---|---|---|
| CAS Number | 108-98-5 | Molecular Weight | 110.177 | |
| Density | 1.1±0.1 g/cm3 | Boiling Point | 169.1±0.0 °C at 760 mmHg | |
| Molecular Formula | C6H6S | Melting Point | -15 °C | |
| MSDS | Chinese USA | Flash Point | 50.6±0.0 °C | |
| Symbol |
GHS02, GHS06, GHS08, GHS09 |
Signal Word | Danger | |
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Localized dealloying corrosion mediated by self-assembled monolayers used as an inhibitor system.
Faraday Discuss. 180 , 191-204, (2015) The structure and chemistry of thiol or selenol self-assembled organic monolayers have been frequently addressed due to the unique opportunities in functionalization of materials. Such organic films can also act as effective inhibition layers to mitigate oxid... |
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Thermophilic Coenzyme B12-Dependent Acyl Coenzyme A (CoA) Mutase from Kyrpidia tusciae DSM 2912 Preferentially Catalyzes Isomerization of (R)-3-Hydroxybutyryl-CoA and 2-Hydroxyisobutyryl-CoA.
Appl. Environ. Microbiol. 81 , 4564-72, (2015) The recent discovery of a coenzyme B12-dependent acyl-coenzyme A (acyl-CoA) mutase isomerizing 3-hydroxybutyryl- and 2-hydroxyisobutyryl-CoA in the mesophilic bacterium Aquincola tertiaricarbonis L108 (N. Yaneva, J. Schuster, F. Schäfer, V. Lede, D. Przybylsk... |
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One-phase controlled synthesis of Au25 nanospheres and nanorods from 1.3 nm Au : PPh3 nanoparticles: the ligand effects.
Nanoscale 7 , 13663-70, (2015) We report the controlled synthesis of [Au25(PPh3)10(SR1)5X2](2+) nanorods (H-SR1: alkyl thiol, H-SC2H4Ph and H-S(n-C6H13)) and Au25(SR2)18 nanospheres (H-SR2: aromatic thiol, H-SPh and H-SNap) under the one-phase thiol etching reaction of the polydisperse Aun... |
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Anionic derivatives of uracil: fragmentation and reactivity.
Phys. Chem. Chem. Phys. 16(33) , 17835-44, (2014) Uracil is an essential biomolecule for terrestrial life, yet its prebiotic formation mechanisms have proven elusive for decades. Meteorites have been shown to contain uracil and the interstellar abundance of aromatic species and nitrogen-containing molecules ... |
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Differentiation of MCF-7 tumor cells from leukocytes and fibroblast cells using epithelial cell adhesion molecule targeted multicore surface-enhanced Raman spectroscopy labels.
J. Biomed. Opt. 20 , 55002, (2015) Identification of tumor and normal cells is a promising application of Raman spectroscopy. The throughput of Raman-assisted cell sorting is limited by low sensitivity. Surface-enhanced Raman spectroscopy (SERS) is a well-recognized candidate to increase the i... |
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Energy level modification in lead sulfide quantum dot thin films through ligand exchange.
ACS Nano 8(6) , 5863-72, (2014) The electronic properties of colloidal quantum dots (QDs) are critically dependent on both QD size and surface chemistry. Modification of quantum confinement provides control of the QD bandgap, while ligand-induced surface dipoles present a hitherto underutil... |
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Total chemical synthesis of human interferon alpha-2b via native chemical ligation.
J. Pept. Sci. 21 , 554-60, (2015) Interferon-alpha (IFNα) is a cytokine that orchestrates innate and adaptive immune responses and potently inhibits proliferation of normal and tumor cells. These properties have warranted the use of IFNα in clinical practice for the treatment of several viral... |
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meso-Tetraphenylporphyrin with a pi-system extended by fusion with anthraquinone.
Org. Biomol. Chem. 13 , 6977-83, (2015) Fusion with a 9,10-anthraquinone moiety was achieved to extend porphyrin's π-system. A bridged dihydroisoindole derivative was used to prepare the corresponding meso-tetraphenyltetraanthraquinonoporphyrin (Ph4TAQP) via a thermal retro-Diels-Alder reaction. Th... |
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Synthesis and antibacterial activity of some novel 4-oxopyrido[2,3-a]phenothiazines.
Arch. Pharm. (Weinheim) 347(11) , 861-72, (2014) A series of substituted 4-oxopyrido[2,3-a]phenothiazine-3-carboxylic acids (6a-d) were prepared via cyclization of the corresponding ethyl 7-(arylthioxy)-8-nitro(or azido)-4-oxoquinoline-3-carboxylates (3a-d/4a-d), followed by hydrolysis of the resultant este... |
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Possible involvement of radical intermediates in the inhibition of cysteine proteases by allenyl esters and amides.
Bioorg. Med. Chem. Lett. 18 , 6202-5, (2008) In order to investigate crystallographically the mechanism of inhibition of cysteine protease by alpha-methyl-gamma,gamma-diphenylallenecarboxylic acid ethyl ester 3, a cysteine protease inhibitor having in vivo stability, we synthesized N-(alpha-methyl-gamma... |