Synthesis

The HF/BF3-catalysed reaction of substituted benzenes with carbon monoxide

JA Willemse, BCB Bezuidenhoudt, CW Holzapfel

Index: Synthesis, , # 15 p. 2543 - 2550

Full Text: HTML

Citation Number: 4

Abstract

... Synthesis 2006(15): 2543-2550 DOI: 10.1055/s-2006-942480. PAPER. © Georg Thieme Verlag Stuttgart · New York ... p-Anisaldehyde (PAA, 1) in particular is an important precursor in the manufacture of 2-ethylhexyl-p-methoxycinnamate [OMC (7), a UV adsorber in sunscreens]. ...

 Related Synthetic Route
carbon monoxide Structure

201230-82-2

carbon monoxide

Chlorobenzene Structure

108-90-7

Chlorobenzene

~31%

4-Chlorobenzaldehyde Structure

104-88-1

4-Chlorobenzaldehyde

2-Chlorobenzaldehyde Structure

89-98-5

2-Chlorobenzaldehyde

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1-Chlorooctane Structure

111-85-3

1-Chlorooctane

~%

1-methyl-3-octyl-imidazolium tetrafluoroborate Structure

244193-52-0

1-methyl-3-octy...

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carbon monoxide Structure

201230-82-2

carbon monoxide

Phenol Structure

108-95-2

Phenol

~79%

4,4'-Methylenediphenol Structure

620-92-8

4,4'-Methylened...

Leucoaurin Structure

603-44-1

Leucoaurin

Detail Learn More
carbon monoxide Structure

201230-82-2

carbon monoxide

Toluene Structure

108-88-3

Toluene

~89%

p-Tolyl ketone Structure

611-97-2

p-Tolyl ketone

Benzenemethanol,4-methyl-a-(4-methylphenyl) Structure

885-77-8

Benzenemethanol...

Detail Learn More
carbon monoxide Structure

201230-82-2

carbon monoxide

Phenol Structure

108-95-2

Phenol

~0%

4,4'-Methylenediphenol Structure

620-92-8

4,4'-Methylened...

Leucoaurin Structure

603-44-1

Leucoaurin

Detail Learn More
carbon monoxide Structure

201230-82-2

carbon monoxide

Anisole Structure

100-66-3

Anisole

~13%

1-[bis(4-methoxyphenyl)methyl]-4-methoxy-benzene Structure

7511-68-4

1-[bis(4-methox...

4-Methoxybenzaldehyde Structure

123-11-5

4-Methoxybenzal...

Detail Learn More
carbon monoxide Structure

201230-82-2

carbon monoxide

Anisole Structure

100-66-3

Anisole

~1%

1-[bis(4-methoxyphenyl)methyl]-4-methoxy-benzene Structure

7511-68-4

1-[bis(4-methox...

4-Methoxybenzaldehyde Structure

123-11-5

4-Methoxybenzal...

Detail Learn More
carbon monoxide Structure

201230-82-2

carbon monoxide

Phenol Structure

108-95-2

Phenol

~0%

4,4'-Methylenediphenol Structure

620-92-8

4,4'-Methylened...

Leucoaurin Structure

603-44-1

Leucoaurin

Detail Learn More
carbon monoxide Structure

201230-82-2

carbon monoxide

Chlorobenzene Structure

108-90-7

Chlorobenzene

~0%

4-Chlorobenzaldehyde Structure

104-88-1

4-Chlorobenzaldehyde

2-Chlorobenzaldehyde Structure

89-98-5

2-Chlorobenzaldehyde

Learn More
carbon monoxide Structure

201230-82-2

carbon monoxide

Toluene Structure

108-88-3

Toluene

~0%

p-Tolyl ketone Structure

611-97-2

p-Tolyl ketone

Benzenemethanol,4-methyl-a-(4-methylphenyl) Structure

885-77-8

Benzenemethanol...

Detail Learn More
1-Hexyl-3-methylimidazolium Chloride Structure

171058-17-6

1-Hexyl-3-methy...

~%

1-Hexyl-3-methylimidazolium Hexafluorophosphate Structure

304680-35-1

1-Hexyl-3-methy...

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chlorohexane Structure

544-10-5

chlorohexane

~%

1-Hexyl-3-methylimidazolium Hexafluorophosphate Structure

304680-35-1

1-Hexyl-3-methy...

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carbon monoxide Structure

201230-82-2

carbon monoxide

Phenol Structure

108-95-2

Phenol

~5%

4,4'-Methylenediphenol Structure

620-92-8

4,4'-Methylened...

Leucoaurin Structure

603-44-1

Leucoaurin

Detail Learn More
carbon monoxide Structure

201230-82-2

carbon monoxide

Toluene Structure

108-88-3

Toluene

~0%

p-Tolyl ketone Structure

611-97-2

p-Tolyl ketone

Benzenemethanol,4-methyl-a-(4-methylphenyl) Structure

885-77-8

Benzenemethanol...

Detail Learn More

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