TRIMETHYLACETIC ANHYDRIDE

Modify Date: 2024-01-02 10:52:41

TRIMETHYLACETIC ANHYDRIDE Structure
TRIMETHYLACETIC ANHYDRIDE structure
Common Name TRIMETHYLACETIC ANHYDRIDE
CAS Number 1538-75-6 Molecular Weight 186.248
Density 1.0±0.1 g/cm3 Boiling Point 193.0±0.0 °C at 760 mmHg
Molecular Formula C10H18O3 Melting Point N/A
MSDS Chinese USA Flash Point 57.2±0.0 °C
Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger

 Names

Name Trimethylacetic anhydride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 193.0±0.0 °C at 760 mmHg
Molecular Formula C10H18O3
Molecular Weight 186.248
Flash Point 57.2±0.0 °C
Exact Mass 186.125595
PSA 43.37000
LogP 1.97
Vapour Pressure 0.5±0.3 mmHg at 25°C
Index of Refraction 1.429
Storage condition Store at RT.

 Safety Information

Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger
Hazard Statements H226-H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C:Corrosive;
Risk Phrases R34
Safety Phrases S26-S36/37/39-S45
RIDADR UN 2920 8/PG 2
WGK Germany 3
Packaging Group II
Hazard Class 8
HS Code 2942000000

 Synthetic Route

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

 Articles10

More Articles
Kinetic resolution of racemic 2-hydroxy-γ-butyrolactones by asymmetric esterification using diphenylacetic acid with pivalic anhydride and a chiral acyl-transfer catalyst.

Org. Lett. 15(6) , 1170-3, (2013)

Various optically active 2-hydroxy-γ-butyrolactone derivatives are produced via the kinetic resolution of racemic 2-hydroxy-γ-butyrolactones with diphenylacetic acid using pivalic anhydride and (R)-be...

The concept of superactive esters. Could peptide synthesis be improved by inventing superactive esters?

Int. J. Pept. Protein Res. 43 , 312, (1994)

According to the concept presented, esters forming an amide (peptide) bond by the mechanism SN#DN or SN#*DN involving fast decay of the tetrahedral intermediate may behave as 'superactive acylating re...

Observation and elimination of N-acetylation of oligonucleotides prepared using fast-deprotecting phosphoramidites and ultra-mild deprotection.

Bioorg. Med. Chem. Lett. 11(9) , 1105-1107, (2001)

Commercially available 'fast-deprotecting' phosphoramidites are useful for synthesizing oligonucleotides containing alkali-sensitive nucleotides. However, N-acetylated oligonucleotides were observed d...

 Synonyms

Pivalic anhydride
MFCD00008842
2,2-dimethylpropanoyl 2,2-dimethylpropanoate
Trimethylacetic Anhydride
2,2-Dimethylpropionic Anhydride
2,2-Dimethylpropanoic anhydride
2,2-Dimethylpropionic anhydride,Pivalic anhydride
EINECS 216-263-1
PROPANOIC ACID, 2,2-DIMETHYL-, ANHYDRIDE
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