4-Nitroisophthalic acid

Modify Date: 2024-01-05 17:55:58

4-Nitroisophthalic acid Structure
4-Nitroisophthalic acid structure
Common Name 4-Nitroisophthalic acid
CAS Number 4315-09-7 Molecular Weight 211.128
Density 1.7±0.1 g/cm3 Boiling Point 492.9±40.0 °C at 760 mmHg
Molecular Formula C8H5NO6 Melting Point 258-259ºC
MSDS N/A Flash Point 222.5±15.8 °C

 Names

Name 4-Nitroisophthalic acid
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.7±0.1 g/cm3
Boiling Point 492.9±40.0 °C at 760 mmHg
Melting Point 258-259ºC
Molecular Formula C8H5NO6
Molecular Weight 211.128
Flash Point 222.5±15.8 °C
Exact Mass 211.011688
PSA 120.42000
LogP 1.59
Vapour Pressure 0.0±1.3 mmHg at 25°C
Index of Refraction 1.660

 MSDS

Material Safety Data Sheet

Section1. Identification of the substance
Product Name: 4-Nitroisophthalic acid
Synonyms:

Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.

Section3. Composition/information on ingredients.
Ingredient name:4-Nitroisophthalic acid
CAS number:4315-09-7

Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

Section7. Handling and storage
Handling:This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Store in closed vessels.
Storage:

Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section9. Physical and chemical properties
Appearance:Not specified
Boiling point:No data
No data
Melting point:
Flash point:No data
Density:No data
Molecular formula:C8H5NO6
Molecular weight:211.1

Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, nitrogen oxides.

Section11. Toxicological information
No data.

Section12. Ecological information
No data.

Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section14. Transportation information
Non-harzardous for air and ground transportation.

Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi
Risk Phrases 36/37/38
Safety Phrases 26-36/37/39
HS Code 2917399090

 Synthetic Route

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4-Nitroisophthalic acid Structure

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CAS#:4315-09-7

Literature: Andrianjara, Charles; Barvian, Nicole Chantel; Gaudilliere, Bernard; Jacobelli, Henri; Ortwine, Daniel Fred; Patt, William Chester; Pham, Ly; Kostlan, Catherine Rose; Wilson, Michael William Patent: US2002/193377 A1, 2002 ; US 20020193377 A1

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CAS#:4315-09-7

Literature: Tetrahedron, , vol. 45, # 5 p. 1311 - 1322

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CAS#:4315-09-7

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 27, p. 277 Journal fuer Praktische Chemie (Leipzig), , vol. <2> 38, p. 313

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4-Nitroisophthalic acid Structure

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CAS#:4315-09-7

Literature: Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 173, p. 161 Bulletin de la Societe Chimique de France, , vol. <4> 29, p. 290,714

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4-Nitroisophthalic acid Structure

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Literature: Helvetica Chimica Acta, , vol. 48, p. 259 - 274

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4-Nitroisophthalic acid Structure

4-Nitroisophtha...

CAS#:4315-09-7

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 27, p. 277 Journal fuer Praktische Chemie (Leipzig), , vol. <2> 38, p. 313 Journal fuer Praktische Chemie (Leipzig), , vol. <2> 22, p. 352 Journal fuer Praktische Chemie (Leipzig), , vol. <2> 25, p. 470 Justus Liebigs Annalen der Chemie, , vol. 153, p. 285

~86%

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CAS#:4315-09-7

Literature: Takeda Chemical Industries, Inc. Patent: US6407116 B1, 2002 ;

~55%

4-Nitroisophthalic acid Structure

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CAS#:4315-09-7

Literature: APPLIED RESEARCH SYSTEMS ARS HOLDING N.V. Patent: WO2004/7491 A1, 2004 ; Location in patent: Page 56-57 ;

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Detail
Literature: Monatshefte fuer Chemie, , vol. 41, p. 155

 Customs

HS Code 2917399090
Summary 2917399090 aromatic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

 Synonyms

4-nitrobenzene-1,3-dicarboxylic acid
4-Nitroisophathalic Acid
4-Nitroisophthalic acid
MFCD00096224
1,3-Benzenedicarboxylic acid, 4-nitro-