2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide

Modify Date: 2024-01-02 20:06:37

2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide structure	Common Name	2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide
	CAS Number	572-09-8	Molecular Weight	411.20
	Density	1.5±0.1 g/cm3	Boiling Point	412.0±45.0 °C at 760 mmHg
	Molecular Formula	C₁₄H₁₉BrO₉	Melting Point	83-88ºC
	MSDS	USA	Flash Point	203.0±28.7 °C

Use of 2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide

α-Acetobromoglucose is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

Name	2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl Bromide
Synonym	More Synonyms

Description	α-Acetobromoglucose is a biochemical reagent that can be used as a biological material or organic compound for life science related research.
Related Catalog	Research Areas >> Others Signaling Pathways >> Others >> Others

Density	1.5±0.1 g/cm3
Boiling Point	412.0±45.0 °C at 760 mmHg
Melting Point	83-88ºC
Molecular Formula	C₁₄H₁₉BrO₉
Molecular Weight	411.20
Flash Point	203.0±28.7 °C
Exact Mass	410.021240
PSA	114.43000
LogP	2.05
Vapour Pressure	0.0±1.0 mmHg at 25°C
Index of Refraction	1.503

2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl Bromide Revision number: 5
(stabilized with CaCO3)
SAFETY DATA SHEET

Section1. IDENTIFICATION
2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl Bromide (stabilized with CaCO3)
Product name:

Revision number:5

Section2. HAZARDS IDENTIFICATION
GHS classification
Not classified
PHYSICAL HAZARDS
HEALTH HAZARDSNot classified
Not classified
ENVIRONMENTAL HAZARDS
GHS label elements, including precautionary statements
None
Pictograms or hazard symbols
Signal wordNo signal word
None
Hazard statements
Precautionary statements:None

Section3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/mixture:Substance
Components:2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl Bromide (stabilized with CaCO3)
Percent:>98.0%(T)
CAS Number:572-09-8
Chemical Formula:C14H19BrO9

Section4. FIRST AID MEASURES
Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical advice/attention if you feel unwell.
Skin contact:Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. If skin irritation or rash occurs: Get medical advice/attention.
Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Ingestion:Get medical advice/attention if you feel unwell. Rinse mouth.
Protection of first-aiders:A rescuer should wear personal protective equipment, such as rubber gloves and air-
tight goggles.

Section5. FIRE-FIGHTING MEASURES
Suitable extinguishingDry chemical, foam, water spray, carbon dioxide.
media:
Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
from the chemical:generate poisonous fume.
2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl
Bromide (stabilized with CaCO3)

Section5. FIRE-FIGHTING MEASURES
Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Remove movable
containers if safe to do so.
When extinguishing fire, be sure to wear personal protective equipment.
Special protective
equipment for firefighters:

Section6. ACCIDENTAL RELEASE MEASURES
Personal precautions,Use personal protective equipment. Keep people away from and upwind of spill/leak.
protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
emergency procedures: roping off, etc.
Environmental precautions: Prevent product from entering drains.
Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
up: appropriate laws and regulations.

Section7. HANDLING AND STORAGE
Precautions for safe handling
Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment.
Prevent dispersion of dust. Wash hands and face thoroughly after handling.
Use a local exhaust if dust or aerosol will be generated.
Advice on safe handling: Avoid contact with skin, eyes and clothing.
Conditions for safe storage, including any
incompatibilities
Storage conditions:Keep container tightly closed. Store in a freezer.
Store under inert gas.
Protect from moisture.
Store away from incompatible materials such as oxidizing agents.
Heat-sensitive, Light-sensitive, Moisture-sensitive
Packaging material:Comply with laws.

Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Install a closed system or local exhaust as possible so that workers should not be
Engineering controls:
exposed directly. Also install safety shower and eye bath.
Personal protective equipment
Respiratory protection: Dust respirator. Follow local and national regulations.
Hand protection:Protective gloves.
Eye protection:Safety glasses. A face-shield, if the situation requires.
Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state (20°C):Solid
Form:Crystal- Powder
Colour:White - Slightly pale yellow
Odour:No data available
pH: No data available
Melting point/freezing point:89°C
No data available
Boiling point/range:
Flash point:No data available
Flammability or explosive
limits:
No data available
Lower:
Upper:No data available
No data available
Relative density:
Solubility(ies):
[Water]No data available
2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl
Bromide (stabilized with CaCO3)

Section9. PHYSICAL AND CHEMICAL PROPERTIES
No data available
[Other solvents]

Section10. STABILITY AND REACTIVITY
Chemical stability:Stable under proper conditions.
Possibility of hazardous No special reactivity has been reported.
reactions:
Incompatible materials: Oxidizing agents
Hazardous decomposition Carbon monoxide, Carbon dioxide, Hydrogen bromide
products:

Section11. TOXICOLOGICAL INFORMATION
No data available
Acute Toxicity:
Skin corrosion/irritation: No data available
No data available
Serious eye
damage/irritation:
Germ cell mutagenicity: No data available
Carcinogenicity:
No data available
IARC =
NTP =No data available
No data available
Reproductive toxicity:

Section12. ECOLOGICAL INFORMATION
Ecotoxicity:
Fish:No data available
Crustacea:No data available
Algae:No data available
Persistence / degradability: No data available
BioaccumulativeNo data available
potential(BCF):
Mobility in soil
Log Pow:No data available
Soil adsorption (Koc):No data available
Henry's LawNo data available
constant(PaM3/mol):

Section13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
Observe all federal, state and local regulations when disposing of the substance.

Section14. TRANSPORT INFORMATION
Hazards Class:Does not correspond to the classification standard of the United Nations
UN-No:Not listed

Section15. REGULATORY INFORMATION
Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
loading and unloading were prescribed.
2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl
Bromide (stabilized with CaCO3)

SECTION 16 - ADDITIONAL INFORMATION
N/A

Hazard Codes	Xi
Risk Phrases	R36/37/38
Safety Phrases	S24/25
RIDADR	NONH for all modes of transport
WGK Germany	-
HS Code	29329985

Precursor 9
CAS#:604-69-3 β-D-Glucose pen... CAS#:2280-44-6 D-glucopyranose CAS#:108-24-7 Ethanoic anhydride CAS#:604-68-2 alpha-D-Glucose...
CAS#:83-87-4 beta-d-glucose ... CAS#:492-62-6 dextrose CAS#:6378-65-0 Hexyl hexanoate CAS#:112-17-4 Decyl acetate
CAS#:4163-65-9 alpha-D-Mannose...
DownStream 9
CAS#:108124-75-0 6-(beta-D-Gluco... CAS#:105088-14-0 zearalenone-4-g... CAS#:474-58-8 Daucosterol CAS#:4098-06-0 3,4,6-Tri-O-ace...
CAS#:498-07-7 Levoglucosan CAS#:709-50-2 METHYL BETA-D-G... CAS#:3323-72-6 a-D-erythro-Hex... CAS#:3366-47-0 2,3,4,5-TETRA-O...
CAS#:38081-37-7 3,4,6-tri-O-ace...

HS Code	29329985

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1-Bromo-a-D-glucose Tetraacetate

MFCD00063254

(2R,3R,4S,5R,6R)-2-(Acetoxymethyl)-6-bromotetrahydro-2H-pyran-3,4,5-triyl triacetate

a-D-Glucopyranosyl Bromide 2,3,4,6-Tetraacetate

EINECS 209-339-0

2,3,4,6-Tetraacetyl-a-D-glucopyranosyl Bromide

α-D-Glucopyranosyl bromide, tetraacetate

a-D-Acetobromoglucose

a-Bromoglucose Tetraacetate

2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl bromid

2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl bromide