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6-苄氨基嘌呤

6-苄氨基嘌呤用途

6-Benzylaminopurine是第一代合成的细胞分裂素,通过刺激细胞分裂引起植物生长和发育,抑制呼吸激酶,从而延长绿色蔬菜的保鲜。

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6-苄氨基嘌呤名称

[ CAS 号 ]:
1214-39-7

[ 中文名 ]:
苄腺嘌呤

[ 英文名 ]:
6-Benzyladenine

[中文别名 ]:

[英文别名 ]:

cylex
6-benzylaminopurine
N-Benzyl-3H-purin-6-amine
N-Benzyladenine
N-(phenylmethyl)-1H-purin-6-amine
benzylaminopurine
benzyladenine
Promalin
6-BA
9H-Purin-6-amine, N-(phenylmethyl)-

6-苄氨基嘌呤生物活性

[ 描述 ]:

6-Benzylaminopurine是第一代合成的细胞分裂素,通过刺激细胞分裂引起植物生长和发育,抑制呼吸激酶,从而延长绿色蔬菜的保鲜。

[ 相关类别 ]:

信号通路 >> 其他 >> 其他

研究领域 >> 其他

[相关活性小分子]

6-苄氨基嘌呤物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
387.5±52.0 °C at 760 mmHg

[ 熔点 ]:
230-233 °C

[ 分子式 ]:
C₁₂H₁₁N₅

[ 分子量 ]:
225.249

[ 闪点 ]:
188.1±30.7 °C

[ 精确质量 ]:
225.101440

[ PSA ]:
66.49000

[ LogP ]:
0.28

[ 外观性状 ]:
白色至淡黄色晶体粉末

[ 蒸汽密度 ]:
>1 (vs air)

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.731

[ 储存条件 ]:
通风低温干燥

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents.

[ 水溶解性 ]:
H2O: soluble

6-苄氨基嘌呤MSDS

详细MSDS(安全技术说明书)

6-苄氨基嘌呤毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AU6252200

CHEMICAL NAME :: Adenine, N-benzyl-

CAS REGISTRY NUMBER :: 1214-39-7

LAST UPDATED :: 199706

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C12-H11-N5

MOLECULAR WEIGHT :: 225.28

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2125 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Behavioral - somnolence (general depressed activity)

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1300 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Behavioral - somnolence (general depressed activity)

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >2300 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Mutation test systems - not otherwise specified

TEST SYSTEM :: Human Leukocyte

DOSE/DURATION :: 10 umol/L

REFERENCE :: EXPEAM Experientia. (Birkhaeuser Verlag, POB 133, CH-4010 Basel, Switzerland) V.1- 1945- Volume(issue)/page/year: 32,29,1976 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

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6-苄氨基嘌呤安全信息

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi: Irritant;Xn: Harmful;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S9-S24/25-S37/39-S26-S36-S23

[ 危险品运输编码 ]:
UN 2348 3/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
UD3150000

[ 包装等级 ]:
I; II; III

[ 海关编码 ]:
2933990090

6-苄氨基嘌呤合成路线

详细合成路线

6-苄氨基嘌呤上下游产品

6-苄氨基嘌呤上游产品

6-苄氨基嘌呤下游产品

6-苄氨基嘌呤制备

制备方法一
以工业中生产病毒唑副产物（Ⅰ）为原料合成。生产过程通过水解、缩合、苄胺化三步化学反应。
水解（次黄嘌呤的制备）。将1400mL3%盐酸和105g（Ⅰ）回流反应8h，加500mL10%氢氧化钠溶液，使pH值5～6。冷却、抽滤得灰黄色固体，用水重结晶，活性炭处理得白色粉末状固体（Ⅱ），干重83g。

缩合（吡啶盐中间体的制备）。将6g（Ⅱ）溶于125mL吡啶溶液，滴加８犿犔三氯氧磷，反应置冰浴中冷却。滴毕继续于室温反应0.5h，即抽滤，干燥后得（Ⅲ）7.85g。

苄胺化（6-BA的合成）。将中间体盐（Ⅲ）置于反应瓶中，滴加30mL苄胺，滴毕水浴升温至60～70℃，反应3h，蒸除苄胺得粗品（Ⅳ）2.1g。重结晶时用1mol/L氢氧化钠溶解粗产物，活性炭煮沸脱色，热过滤，冷后调节pH值4～5，有白色固体析出。上述各步反应过程如下。

制备方法二
通过次黄嘌呤氯代，然后苄胺解制得苄基腺嘌呤。

制备方法三

制备方法四
由腺嘌呤与氯苄直接反应制得，但产品中9-位取代物难以分离和纯化。

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6-苄氨基嘌呤海关

[ 海关编码 ]: 2933990090

[ 中文概述 ]:
2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

6-苄氨基嘌呤文献

Improved ethanol tolerance and ethanol production from glycerol in a streptomycin-resistant Klebsiella variicola mutant obtained by ribosome engineering.

Bioresour. Technol. 176 , 156-62, (2014)

To improve the ethanol tolerance of the Klebsiella variicola strain TB-83, we obtained the streptomycin-resistant, ethanol-tolerant mutant strain TB-83D by a ribosome engineering approach. Strain TB-8...

Recombinant canine single chain insulin analogues: insulin receptor binding capacity and ability to stimulate glucose uptake.

Vet. J. 202(3) , 436-42, (2014)

Virtually all diabetic dogs require exogenous insulin therapy to control their hyperglycaemia. In the UK, the only licensed insulin product currently available is a purified porcine insulin preparatio...

A family of cationic polyamides for in vitro and in vivo gene transfection.

Acta Biomater. 22 , 120-30, (2015)

The purpose of this study is to develop biodegradable cationic polyamides for non-viral gene delivery and elucidate their structural effects on gene transfection activity. To this end, a group of nove...

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6-苄氨基嘌呤

6-苄氨基嘌呤用途

6-苄氨基嘌呤名称

6-苄氨基嘌呤生物活性

6-苄氨基嘌呤物理化学性质

6-苄氨基嘌呤MSDS

详细MSDS(安全技术说明书)

6-苄氨基嘌呤毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

6-苄氨基嘌呤安全信息

6-苄氨基嘌呤合成路线

详细合成路线

6-苄氨基嘌呤上下游产品

6-苄氨基嘌呤上游产品

6-苄氨基嘌呤下游产品

6-苄氨基嘌呤制备

6-苄氨基嘌呤海关

6-苄氨基嘌呤文献

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