General Copper??Catalyzed Transformations of Functional Groups from Arylboronic Acids in Water

H Yang, Y Li, M Jiang, J Wang…

Index: Yang, Haijun; Li, Yong; Jiang, Min; Wang, Junmei; Fu, Hua Chemistry - A European Journal, 2011 , vol. 17, # 20 p. 5652 - 5660

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Citation Number: 131

Abstract

Abstract A simple and general copper-catalyzed method has been developed for transformations of various functional groups ([BOND] I,[BOND] N 3,[BOND] SO 2 R,[BOND] OH,[BOND] NH 2, and [BOND] NO 2) on aromatic rings from arylboronic acids in water under air. The protocol uses cheap and readily available inorganic salts (KI, NaN 3, NaSO 2 R, NaOH, NaNO 2) and aqueous ammonia as the functional-group sources, simple Cu 2 O/ ...

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