Synthesis of DMSO-SbCl5 (1: 1) complex and its oxidizing action toward alcohols.

J Yamamoto, S Ito, T Tsuboi, T Tsuboi…

Index: Yamamoto, Jiro; Ito, Satoshi; Tsuboi, Takashi; Tsuboi, Toshiaki; Tsukihara, Kumiko Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 2 p. 470 - 472

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Citation Number: 21

Abstract

From an equimolar mixture of DMSO and SbCl 5 in carbon tetrachloride, a DMSO–SbCl 5 (1: 1) complex (1) was formed as a white precipitate in a quantitative yield. The structure of 1 was determined by X-ray crystallographic analysis. Butyraldehydes, para-substituted benzaldehydes and benzils were obtained by the oxidation of butylalcohols, para- substituted benzylalcohols and benzoins using 1 as an oxidizing agent.

~10%

~75%

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~42%

~96%

~51%

~77%

~44%

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