Synthesis of DMSO-SbCl5 (1: 1) complex and its oxidizing action toward alcohols.

J Yamamoto, S Ito, T Tsuboi, T Tsuboi…

Index: Yamamoto, Jiro; Ito, Satoshi; Tsuboi, Takashi; Tsuboi, Toshiaki; Tsukihara, Kumiko Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 2 p. 470 - 472

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Citation Number: 21

Abstract

From an equimolar mixture of DMSO and SbCl 5 in carbon tetrachloride, a DMSO–SbCl 5 (1: 1) complex (1) was formed as a white precipitate in a quantitative yield. The structure of 1 was determined by X-ray crystallographic analysis. Butyraldehydes, para-substituted benzaldehydes and benzils were obtained by the oxidation of butylalcohols, para- substituted benzylalcohols and benzoins using 1 as an oxidizing agent.

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p-chlorobenzylalcohol Structure

873-76-7

p-chlorobenzyla...

~10%

dms Structure

75-18-3

dms

4-Chlorobenzaldehyde Structure

104-88-1

4-Chlorobenzaldehyde

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2,2'-Furoin Structure

552-86-3

2,2'-Furoin

~75%

dms Structure

75-18-3

dms

Furil Structure

492-94-4

Furil

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2-Hydroxy-1,2-bis(4-methoxyphenyl)ethanone Structure

119-52-8

2-Hydroxy-1,2-b...

~0%

dms Structure

75-18-3

dms

4,4'-Dimethoxybenzil Structure

1226-42-2

4,4'-Dimethoxybenzil

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2,2'-Furoin Structure

552-86-3

2,2'-Furoin

~0%

dms Structure

75-18-3

dms

Furil Structure

492-94-4

Furil

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(±)-2-Butanol Structure

78-92-2

(±)-2-Butanol

~0%

dms Structure

75-18-3

dms

2-Butanone Structure

78-93-3

2-Butanone

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Butanol Structure

71-36-3

Butanol

~0%

dms Structure

75-18-3

dms

Butyraldehyde Structure

123-72-8

Butyraldehyde

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isobutanol Structure

78-83-1

isobutanol

~0%

dms Structure

75-18-3

dms

Isobutyraldehyde Structure

78-84-2

Isobutyraldehyde

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2-hydroxy-1,2-bis(2-nitrophenyl)ethanone Structure

59163-44-9

2-hydroxy-1,2-b...

~0%

dms Structure

75-18-3

dms

1,2-bis(2-nitrophenyl)ethane-1,2-dione Structure

133253-56-2

1,2-bis(2-nitro...

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Benzoin Structure

119-53-9

Benzoin

~0%

dms Structure

75-18-3

dms

Benzil Structure

134-81-6

Benzil

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Ethanone,2-hydroxy-1,2-bis(4-methylphenyl) Structure

1218-89-9

Ethanone,2-hydr...

~0%

dms Structure

75-18-3

dms

4,4'-dimethylbenzil Structure

3457-48-5

4,4'-dimethylbenzil

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p-tolylmethanol Structure

589-18-4

p-tolylmethanol

~0%

dms Structure

75-18-3

dms

p-Tolualdehyde Structure

104-87-0

p-Tolualdehyde

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(4-Nitrophenyl)methanol Structure

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(4-Nitrophenyl)...

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dms Structure

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dms

4-Nitrobenzaldehyde Structure

555-16-8

4-Nitrobenzaldehyde

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p-chlorobenzylalcohol Structure

873-76-7

p-chlorobenzyla...

~0%

dms Structure

75-18-3

dms

4-Chlorobenzaldehyde Structure

104-88-1

4-Chlorobenzaldehyde

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Benzyl alcohol Structure

100-51-6

Benzyl alcohol

~0%

dms Structure

75-18-3

dms

Benzaldehyde Structure

100-52-7

Benzaldehyde

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isobutanol Structure

78-83-1

isobutanol

~42%

dms Structure

75-18-3

dms

Isobutyraldehyde Structure

78-84-2

Isobutyraldehyde

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2-Hydroxy-1,2-bis(4-methoxyphenyl)ethanone Structure

119-52-8

2-Hydroxy-1,2-b...

~96%

dms Structure

75-18-3

dms

4,4'-Dimethoxybenzil Structure

1226-42-2

4,4'-Dimethoxybenzil

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(±)-2-Butanol Structure

78-92-2

(±)-2-Butanol

~51%

dms Structure

75-18-3

dms

2-Butanone Structure

78-93-3

2-Butanone

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Ethanone,2-hydroxy-1,2-bis(4-methylphenyl) Structure

1218-89-9

Ethanone,2-hydr...

~77%

dms Structure

75-18-3

dms

4,4'-dimethylbenzil Structure

3457-48-5

4,4'-dimethylbenzil

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(4-Nitrophenyl)methanol Structure

619-73-8

(4-Nitrophenyl)...

~44%

dms Structure

75-18-3

dms

4-Nitrobenzaldehyde Structure

555-16-8

4-Nitrobenzaldehyde

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